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Irreversible Performance of a Quantum Harmonic Heat Engine

机译:量子谐波热机的不可逆性能

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摘要

The unavoidable irreversible losses of power in a heat engine are found to be of quantum origin. Following thermodynamic tradition a model quantum heat engine operating by the Otto cycle is analyzed. The working medium of the model is composed of an ensemble of harmonic oscillators. A link is established between the quantum observables and thermodynamical variables based on the concept of canonical invariance. These quantum variables are sufficient to determine the state of the system and with it all thermodynamical variables. Conditions for optimal work, power and entropy production show that maximum power is a compromise between the quasistatic limit of adiabatic following on the compression and expansion branches and a sudden limit of very short time allocation to these branches. At high temperatures and quasistatic operating conditions the efficiency at maximum power coincides with the endoreversible result. The optimal compression ratio varies from the square root of the temperature ratio in the quasistatic limit where their reversibility is dominated by heat conductance to the temperature ratio to the power of 1/4 in the sudden limit when the irreversibility is dominated by friction. When the engine deviates from adiabatic conditions the performance is subject to friction. The origin of this friction can be traced to the noncommutability of the kinetic and potential energy of the working medium.
机译:发现热机中不可避免的不可逆功率损失是量子起源的。遵循热力学传统,分析了通过奥托循环运行的量子量子热机模型。该模型的工作介质由一组谐波振荡器组成。基于规范不变性的概念,在量子可观测量和热力学变量之间建立了联系。这些量子变量足以确定系统的状态以及所有热力学变量。最佳功,功率和熵产生的条件表明,最大功率是压缩和扩展分支上绝热的准静态极限与为这些分支分配非常短的时间的突然极限之间的折衷。在高温和准静态操作条件下,最大功率下的效率与可逆结果相吻合。最佳压缩比从准静态极限的温度比的平方根变化(在准静态极限中,它们的可逆性由导热率决定)到温度比,在突然极限时的温度比至1/4的幂,而不可逆性由摩擦决定。当发动机偏离绝热条件时,性能会受到摩擦。这种摩擦的根源可以追溯到工作介质的动能和势能的不可交换性。

著录项

  • 作者

    Rezek, Y; Kosloff, R;

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  • 年度 2006
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  • 原文格式 PDF
  • 正文语种 eng
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